Chemical & Process Water & Desalination Calculation guide Understand a concept

Setting up a mass balance and knowing when it does not close

Conservation of mass across a process, and the arithmetic checks that catch an error before design does.

The engineering question

A mass balance will not close. Which stream is wrong, and is it a measurement or a model?

Worked example

The figures below were produced by running the Plant Mass Balance with the same inputs .

These figures are worked by the published method rather than executed at build time, because this tool is a self-contained page calculator without a programmatic engine.

  1. Total mass in equals total mass out; only the species balance moves.
  2. The closing stream is calculated, not measured — and it absorbs every error upstream.
  3. A closing stream outside its plausible range means the measurement, not the model, is at fault.

Sanity check

If the closing stream comes out negative, one of the measured flows or concentrations is wrong. No model fixes that.

Tools for this problem

These are the EngiMetric calculators that compute the numbers in this topic. Each one shows its formula, its units and its limits rather than returning a bare result.

References & standards

  • Felder, Rousseau & Bullard — Elementary Principles of Chemical Processes
  • ISO 45012 — water balance

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